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New radiometric ages from the Subpenninic nappes (Eclogite Zone and Rote Wand – Modereck Nappe, Tauern Window) show that phengites formed under eclogite-facies metamorphic conditions retain their initial isotopic signature, even when associated lithologies were overprinted by greenschist- to amphibolite-facies metamorphism. Different stages of the eclogite-facies evolution can be dated provided 40Ar/39Ar dating is combined with micro-structural analyses. An age of 39 Ma from the Rote Wand – Modereck Nappe is interpreted to be close to the burial age of this unit. Eclogite deformation within the Eclogite Zone started at the pressure peak along distinct shear zones, and prevailed along the exhumation path. An age of ca. 38 Ma is only observed for eclogites not affected by subsequent deformation and is interpreted as maximum age due to the possible influence of homogenously distributed excess argon. During exhumation deformation was localised along distinct mylonitic shear zones. This stage is mainly characterised by the formation of dynamically recrystallized omphacite2 and phengite. Deformation resulted in the resetting of the Ar isotopic system within the recrystallized white mica. Flat argon release spectra showing ages of 32 Ma within mylonites record the timing of cooling along the exhumation path, and the emplacement onto the Venediger Nappe. Ar-release patterns and 36Ar/40Ar vs.39Ar/40Ar isotope correlation analyses indicate no significant 40Ar-loss after initial closure, and only a negligible incorporation of excess argon. From the pressure peak onwards, eclogitic conditions prevailed for almost 8–10 Ma.  相似文献   
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Asymmetric magnetic field configurations in solar active regions hinder mildly relativistic electrons with magnetic moments suitable to produce microwave radiation from being trapped. Therefore the duration of stay of electrons in the microwave source region is much shorter (<0.2 s) than in the usually assumed trapping models. On this basis we construct a consistent model of hard X-ray correlated microwave bursts due to continuous injection of electrons into a pole field of an asymmetric magnetic loop (Figures 1 and 2). This resolves the discrepancy of the numbers of electrons needed to produce X-ray and radio emission.We compute gyrosynchrotron spectra with the assumption of conservation of the magnetic moment M in the microwave source. The consequence is an anticorrelation between the low frequency power index a of the microwave spectrum and the power index of the hard X-ray spectrum. In fact during the flare of May 18, 1972 increases with time while a is decreasing, so that +a= constant. Furthermore, it is shown that electrons with energies below 100 keV contribute significantly to the microwave radiation; they determine the low frequency spectrum completely.The model is able to explain the most often observed type C-spectra (Guidice and Castelli, 1975), but also flat spectra over one frequency decade.On leave from University of Berne, Institute of Applied Physics.  相似文献   
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Hydration of organic coatings in soils is expected to affect the sorption of oxyanions onto hydrous Fe and Al oxides. We hypothesized that the hydration of polygalacturonate (PGA) coatings on alumina (Al2O3) increases their permeability for phosphate. Pure and PGA-coated alumina were equilibrated in deionized water for 2 and 170 h at pH 5 and 20 °C before studying (i) their porosity with N2 gas adsorption and 1H NMR relaxometry, (ii) structural changes of PGA-coatings with differential scanning calorimetry (DSC), and (iii) the kinetics of phosphate sorption and PGA desorption in batch experiments. Scanning electron micrographs revealed that PGA molecules formed three-dimensional networks with pores ranging in size from <10 to several hundred nanometers. Our NMR results showed that the water content of intraparticle alumina pores decreased upon PGA sorption, indicating a displacement of pore water by PGA. The amount of water in interparticle alumina pores increased strongly after PGA addition, however, and was attributed to water in pores of PGA and/or in pores at the PGA-alumina interface. The flexibility of PGA molecules and the fraction of a PGA gel phase increased within one week of hydration, implying restructuring of PGA. Hydration of PGA coatings increased the amount of phosphate defined as instantaneously sorbed by 84%, showing that restructuring of PGA enhanced the accessibility of phosphate to external alumina surfaces. Despite the fact that the efficacy of phosphate to displace PGA was higher after 170 h than after 2 h, a higher phosphate surface loading was required after 170 h to set off PGA desorption. Our findings imply that the number of PGA chain segments directly attached to the alumina surface decreased with time. We conclude that hydration/dehydration of polymeric surface coatings affects the sorption kinetics of oxyanions, and may thus control the sorption and transport of solutes in soils.  相似文献   
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The first discovery of dinosaur footprints on the Dalmatian part of the Adriatic-Dinaric carbonate platform (ADCP) is reported. They constitute the geologically youngest record of footprints on the ADCP. The trackbearing layer was formed in the intertidal environment and represents the final stage of a shallowing-upward cycle. Just below it, a heavy dinoturbated limestone layer can be observed. Microfacies analysis, incorporating evidence from benthic foraminifera and algae, indicates a Late Turonian–Early Coniacian age. The overall morphology and size of the footprints points to sauropod dinosaurs; they represent the largest forms recorded so far on the ADCP. This hints at a prolonged sauropod presence on the platform and to its Late Cretaceous connection to the continent rather than isolation.  相似文献   
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